Reaction of carbon monoxide with alkyliron porphyrins generated from alkyl halides and electrochemically produced Iron(I) and Iron(''O'') porphyrins

Article abstract of DOI:10.1021/ja00161a035

Carbon monoxide inserts in iron-carbon bonds of σ-alkyl porphyrins generated from the reaction of alkyl halides with electrochemically produced low-valent iron porphyrins, with the exception of benzyl derivatives. In the case of σ-aryl complexes, the iron