Journal of Organic Chemistry p. 3856 - 3859 (1981)
Update date:2022-08-04
Topics:
Kano, Shinzo
Sugino, Eiichi
Shibuya, Shiroshi
Hibino, Satoshi
2-(1-Cyclohexenyl)-3-(β-methoxyvinyl)indole was heated in decalin in the presence of 5percent Pd-C to give 1,2,3,4-tetrahydro-5-methoxy-11H-benzocarbazole and 5-methoxy-11H-benzocarbazole. 3-(β-Methoxyvinyl)-2-(1-phenyl-1-propenyl)indole and 5-chloro-3-(β-methoxyvinyl)-2-(1-phenyl-1-propenyl)indole were also heated in decalin in the presence of 5percent Pd-C at 210 deg C, yielding the carbazole alkaloids hyellazole and 6-chlorohyellazole, respectively.
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