ANTIMONY-121 MOESSBAUER AND INFRARED SPECTRAL STUDY ON HALOPHENYLANTIMONATE(III) COMPOUNDS

DOI: 10.1016/S0022-328X(00)86646-2

Source and publish data:

Journal of Organometallic Chemistry p. 63 - 68 (1981)

Update date:2022-07-30

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Authors:

Alonzo, G.

Bertazzi, N.

Bianca, F. Di

Gibb, T.C.

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Article abstract of DOI:10.1016/S0022-328X(00)86646-2

The synthesis and the 121Sb Moessbauer and infrared spectra of the halophenylantimonates(III) M (M=Me4N, Ph4As; X=Cl, Br, I) are reported, and the spectral data are discussed and compared with those of SbX^-4 and other related systems.The results are in accord with the participation of the antimony 5s electrons in the Sb-Ph bond.In the interpretation of the electric field gradient, the contributions to V_zz from both the lone pair and the Sb-Ph bond electron densities are assumed to be dominant.

Full text of DOI:10.1016/S0022-328X(00)86646-2

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