Helvetica Chimica Acta p. 407 - 424 (1981)
Update date:2022-08-04
Topics:
Kaiser, Hanspeter
Keller-Schierlein, Walter
The structure of the antibiotic elaiophylin (azalomycin B) was elucidated by extended spectroscopic investigations and chemical degradation.Elaiophylin (26) is a macrodiolide with a 16 membered dilactone ring.The synthesis of 7-acetoxy-6-ethyl-3-octanone (14), the acetyl derivative of an important degradation product, is described.
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