Reactions of Ketones with Molybdenum Nitrosyl Complexes: X-Ray Crystal Structures of (NO)I>2O>, a Complex having a Bent Mo-O-Mo Bond, and of a Bicyclic Salt, 1/2(I3)1/2>

DOI: 10.1039/c39810000348

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 348 - 350 (1981)

Update date:2022-07-30

Topics:

Authors:

Adams, Harry

Bailey, Neil A.

Denti, Gianfranco

McCleverty, Jon A.

Smith, John M. A.

Wlodarczyk, Andrzej

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Article abstract of DOI:10.1039/c39810000348

Reaction of (NO)I2> with refluxing acetone or diacetone alcohol led to C-C bond cleavage and formation, in low yield, of <(NO)I>2(μ-O)> and the bicyclic cation + (isolated as the I- or mixed I-/I3- salt); the structures of the last two were determined crystallographically, the μ-oxo species having a slightly bent Mo-O-Mo bond.

Full text of DOI:10.1039/c39810000348

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