Tetrahedron Letters p. 1697 - 1700 (1981)
Update date:2022-09-26
Topics:
Saito, Isao
Nakata, Akira
Matsuura, Teruo
1,3-Di-tert-butylisobenzofuran reacts with singlet oxygen with rate constant of 2.8E9 M-1 sec-1 to give stable endoperoxide 4.Thermolysis of the endoperoxide (4) in the presence of norbornene and naphthalene gave the corresponding epoxide and naphthols, respectively.Addition of Pd(OAc)2 improved the yield of naphthols considerably.
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Doi:10.1021/jo01351a048
(1961)Doi:10.1246/bcsj.54.1844
(1981)Doi:10.1016/S0040-4039(01)90501-5
(1981)Doi:10.1039/jr9470000634
(1947)Doi:10.1021/ol048494i
(2004)Doi:10.1038/nchem.1408
(2012)