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Preparation, characterization, and some reactions of tri-tert-butylarsine complexes of platinum(II) and palladium(II) chlorides

DOI: 10.1021/ic50225a006

Source and publish data:

Inorganic Chemistry p. 3611 - 3616 (1981)

Update date:2022-08-02

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Authors:

Goel, Ram G.Goel, Ram G.

Ogini, William O.Ogini, William O.

Srivastava, Ramesh C.Srivastava, Ramesh C.

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Article abstract of DOI:10.1021/ic50225a006

As(t-Bu)3 reacts with platinum(II) chlorides to afford either trans-PtCl2[As(t-Bu)3]2 or the dinuclear complex Pt2(μ-Cl)2Cl2[As(t-Bu)3] 2. With palladium(II) chloride, however, only the dinuclear complex Pd2(μ-Cl)2Cl2[As(t-Bu)3] 2 is formed even in the presence of excess As(t-Bu)3. These complexes undergo substitution and/or bridge-cleavage reactions with CO, py, AsPh3, Cl-, or tertiary phosphines.

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Full text of DOI:10.1021/ic50225a006

Products guided by the article

Product name:[As(C6H5)4](1+)*[PtCl3(As(C(CH3)3)3)](1-)=[As(C6H5)4][PtCl3(As(C(CH3)3)3)]

Cas No:78610-13-6

78610-13-6

R&D Labs maybe for 78610-13-6

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