Inorganic Chemistry p. 3611 - 3616 (1981)
Update date:2022-08-02
Topics:
Goel, Ram G.
Ogini, William O.
Srivastava, Ramesh C.
As(t-Bu)3 reacts with platinum(II) chlorides to afford either trans-PtCl2[As(t-Bu)3]2 or the dinuclear complex Pt2(μ-Cl)2Cl2[As(t-Bu)3] 2. With palladium(II) chloride, however, only the dinuclear complex Pd2(μ-Cl)2Cl2[As(t-Bu)3] 2 is formed even in the presence of excess As(t-Bu)3. These complexes undergo substitution and/or bridge-cleavage reactions with CO, py, AsPh3, Cl-, or tertiary phosphines.
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Doi:10.1021/jo00335a014
(1981)Doi:10.1248/cpb.29.1473
(1981)Doi:10.1016/S0040-4020(03)00616-1
(2003)Doi:10.1021/jo00335a047
(1981)Doi:10.1246/cl.1981.267
(1981)Doi:10.1021/jo00335a024
(1981)
