ChemCatChem p. 2350 - 2354 (2019)
Update date:2022-08-02
Topics:
Li, Fang-Yuan
Lin, Dian-Zhao
He, Tian-Jun
Zhong, Wei-Qiang
Huang, Jing-Mei
A new method for the synthesis of vinyl trifluoromethyl compounds from α, β-unsaturated carboxylic acids and CF3SO2Na has been developed. This electrochemical decarboxylative trifluoro-methylation was found to be highly stereoselective and afforded products in good yields with wide substrate scope under metal-free and external chemical oxidant-free conditions.
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