ON THE ROTATION VERSUS THE INVERSION MECHANISM IN THE THERMAL ISOMERIZATION OF CIS-AZOBENZENES

DOI: 10.1246/cl.1980.1303

Source and publish data:

Chemistry Letters p. 1303 - 1306 (1980)

Update date:2022-09-26

Topics:

Authors:

Shinkai, Seiji

Kusano, Yumiko

Shigematsu, Kazuyoshi

Manabe, Osamu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1980.1303

The thermal cis-to-trans isomerization of an azobenzene covalently-bridged to azacrown ether occurs via the inversion mechanism, and the rotational mechanism is not allowed owing to the rigid ring structure.By using the "standard" azobenzene, it was demon

Full text of DOI:10.1246/cl.1980.1303

Products guided by the article

Product name:4,4'-bis(morpholinocarbonyl)azobenzene

Cas No:78679-98-8

R&D Labs maybe for 78679-98-8

TIANJIN FESTO CHEMICAL CO.,LTD(expird)

Contact:86-22-25814570

Address:No.12th,5th Ave.,TEDA,Tianjin,China
Chengdu Pukang Biotechnology Co., Ltd

website:http://www.pu-kang.com

Contact:86-028-63976226

Address:No. 868 Xiwang Road,Xinjin county,Chengdu city, China
Valiant Fine Chemicals Co., Ltd.

Contact:+86 535 6101878/6374484

Address:11 Wuzhishan Rd.,YTETDZ,Yantai,264006,Shandong,China
CHANGZHOU HANGYU PHARMACEUTICAL TECHNOLOGY CO., LTD

website:http://www.czyys.com

Contact:0086-519-88802789

Address:No.300,Yanling Middle Road, Changzhou, Jiangsu, China
Shanghai Standard Biotech Co., Ltd.

Contact:+86-18502101150

Address:Room 103, Building 2nd, NO.720, Cailun Road , Pudong District, Shanghai, China

Relevant to this article

Doi:10.1021/je60007a029
(1960)
Evaluation of sparteine-like chiral diamines in the enantioselective lithiation-electrophilic trapping of an O-alkyl carbamate

Doi:10.1039/b600032k
(2006)
STUDIES ON ORGANOPHOSPHORUS COMPOUNDS - XXXV. A NEW ROUTE TO 4-METHOXYPHENYLPHOSPHONOTHIOIC DIAMIDES FROM 2,4-BIS(4-METHOXYPHENYL)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE AND AMINES

Doi:10.1016/S0040-4020(01)97679-3
(1981)
Flow rhodaelectro-catalyzed alkyne annulations by versatile C-H Activation: Mechanistic support for rhodium(III/IV)

Doi:10.1021/jacs.9b07763
(2019)
TETRAPHENYLCYCLOBUTADIEN ALS LIGAND IN NICKEL(I)-KOMPLEXEN

Doi:10.1016/S0022-328X(00)82969-1
(1981)
Synthesis of 1- and 3-(1-substituted 4-piperidinyl)-1,2,3,4-tetrahydro-2-oxoquinazolines as potential antihypertensive agents

Doi:10.1248/cpb.33.1116
(1985)

Article Doi