ON THE ROTATION VERSUS THE INVERSION MECHANISM IN THE THERMAL ISOMERIZATION OF CIS-AZOBENZENES

DOI: 10.1246/cl.1980.1303

Source and publish data:

Chemistry Letters p. 1303 - 1306 (1980)

Update date:2022-09-26

Topics:

Authors:

Shinkai, Seiji

Kusano, Yumiko

Shigematsu, Kazuyoshi

Manabe, Osamu

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Article abstract of DOI:10.1246/cl.1980.1303

The thermal cis-to-trans isomerization of an azobenzene covalently-bridged to azacrown ether occurs via the inversion mechanism, and the rotational mechanism is not allowed owing to the rigid ring structure.By using the "standard" azobenzene, it was demon

Full text of DOI:10.1246/cl.1980.1303

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