Cyclopentadienyl-ruthenium and -osmium chemistry. Cleavage of Tetracyanoethylene under Mild Conditions: X-Ray Crystal Structures of 3-C(CN)2CPhC=C(CN)2>(PPh3)(η-C5H5)> and CPh=C(CN)2>(CNBut)(PPh3)(η-C5H5)>

DOI: 10.1039/c39810000271

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 271 - 272 (1981)

Update date:2022-09-26

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Authors:

Bruce, Michael I.

Rodgers, John R.

Snow, Michael R.

Swincer, A. Geoffrey

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Article abstract of DOI:10.1039/c39810000271

The reaction between and C2(CN)4 affords 3-C(CN)2CPhC=C(CN)2>(PPh3)(η-C5H5)> (2), which forms CPh=C(CN)2>(L)(PPh3)(η-C5H5)> (5) with L = CO or CNBu^t; the structures of (2) and (5; L = CNBu

Full text of DOI:10.1039/c39810000271

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