SYNTHESES OF (+/-)-AKLAVINONES. APPLICATION OF THE STEREOCONTROLLED "ZIPPER" BICYCLO-CYCLIZATION REACTION

DOI: 10.1016/S0040-4020(01)91535-2

Source and publish data:

Tetrahedron p. 4725 - 4742 (1984)

Update date:2022-09-26

Topics:

Authors:

Uno, Hidemitsu

Naruta, Yoshinori

Maruyama, Kazuhiro

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Article abstract of DOI:10.1016/S0040-4020(01)91535-2

Efficient syntheses of (+/-)-aklavinones; (+/-)-aklavinone (1), (+/-)-auramycinone (2), and (+/-)-13-methylaklavinone (3), are described.A key process of the tetracyclic ring construction in these syntheses is a stereocontrolled "zipper" bicyclo-cyclizati

Full text of DOI:10.1016/S0040-4020(01)91535-2

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