THE REACTION OF VINYL AZIDES WITH SULFOXONIUM YLIDS. SYNTHESIS OF N-VINYL TRIAZOLINES AND VINYL AZIRIDINES.

DOI: 10.1016/S0040-4039(01)90462-9

Source and publish data:

Tetrahedron Letters p. 1863 - 1866 (1981)

Update date:2022-08-03

Topics:

Authors:

Hassner, Alfred

Belinka, Benjamin A.

Haber, Mark

Munger, Paul

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Article abstract of DOI:10.1016/S0040-4039(01)90462-9

Vinyl azides 1 react with dimethylsulfoxonium ylid 3 at the azide function to produce in high yield 1-vinyl-4,5-unsubstituted-Δ²-1,2,3-triazolines 4.Vacuum flash pyrolysis of 4 furnished N-vinylaziridines 7 without formation of pyrrolines.

Full text of DOI:10.1016/S0040-4039(01)90462-9

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