Mixed-metal cluster chemistry III . P-C activation at tungsten-triiridium cores; X-ray crystal structures of [CpWIr3 {μ3-η2-PPh(C6H4)} (μ-CO)2(CO) 7]

DOI: 10.1016/0022-328X(95)06070-D

Source and publish data:

Journal of Organometallic Chemistry p. 89 - 98 (1996)

Update date:2022-08-05

Topics:

Authors:

Waterman, Susan M.

Tolhurst, Vicki-Anne

Humphrey, Mark G.

Skelton, Brian W.

White, Allan H.

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Article abstract of DOI:10.1016/0022-328X(95)06070-D

The thermolysis of [CpWIr₃(μ-CO)₃(CO)₇(PPh₃)] in refluxing toluene gives [CpWIr₃{μ₃-η²-PPh(C₆H₄)}(μ-CO)₂(CO)₇] (1) in good yield (56%)

Full text of DOI:10.1016/0022-328X(95)06070-D

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