PHOTOLYSIS OF ORGANOPOLYSILANES. THE REACTION OF PHOTOCHEMICALLY GENERATED TRIMETHYLSILYLPHENYLSILYLENE WITH ALKYL CHLORIDES

DOI: 10.1016/S0022-328X(00)85825-8

Source and publish data:

Journal of Organometallic Chemistry p. C48 - C50 (1981)

Update date:2022-09-26

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Authors:

Ishikawa, Mitsuo

Nakagawa, Ken-Ichi

Katayama, Seiji

Kumada, Makoto

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Article abstract of DOI:10.1016/S0022-328X(00)85825-8

Photochemically generated trimethylsilylphenylsilylene reacted with octyl chloride and cyclopropylcarbinyl chloride to give the respective formal carbon-chlorine insertion products.With sec-butyl chloride, trimethylsilylphenylsilylene afforded both the carbon-chlorine insertion product and 1-chloro-1-phenyl-2,2,2-trimethyldisilane (IV), while with tert-butyl chloride, IV was obtained as the sole volatile product.

Full text of DOI:10.1016/S0022-328X(00)85825-8

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