Tetrahedron Letters p. 51 - 54 (1995)
Update date:2022-09-26
Topics:
Moriarty, Robert M.
Kim, Joonggon
Brumer, Harry
The enyne needed for coupling to a CD-ring fragment, namely, 3S,5R-oct-1-en-7-yne-3,5-diol, in the Trost-Dumas carbopalladation route to 1α,25-dihydroxyvitamin D3 was synthesized from D-xylose in 13 steps and 21percent yield.
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