Tetrahedron p. 383 - 387 (1981)
Update date:2022-08-05
Topics:
Croft, K. D.
Ghisalberti, E. L.
Jefferies, P. R.
Stuart, A. D.
The absolute configuration of the dicipiene diterpenes has been determined by degradation to 4R-4-(2-methoxy-4-methylphenyl)-pentanoic acid.Photolysis of 1,18-diacetoxy-13-oxodecipi-14-ene proceeds through a novel photochemical reaction, formally a <2+2> cycloreversion, to generate a key intermediate for the degradation.
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Doi:10.1016/j.jorganchem.2004.07.063
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(1982)Doi:10.1039/P19810002666
(1981)Doi:10.1021/jo00341a019
(1982)Doi:10.1016/j.tet.2004.08.099
(2004)
