HETEROATOMIC DERIVATIVES OF AZIRIDINE. 12. REACTION OF 1-(CARBOMETHOXYALKYL)AZIRIDINES WITH THIOLS AND MERCAPTO ACIDS

DOI: 10.1007/BF00506034

Source and publish data:

Chemistry of Heterocyclic Compounds p. 679 - 681 (1981)

Update date:2022-09-26

Topics:

Authors:

Voronkov, M. G.

Knutov, V. I.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1007/BF00506034

The reaction of 1-(carbomethoxyalkyl)aziridines with thiols and mercapto acids, which leads to the formation of the corresponding sulfides and esters of S-substituted N-(2-mercaptoethyl)amino acids, was studied.The acid hydrolysis of o-<(N-carbomethoxyethyl)-2-aminoethylthio>benzoic acid and o-<(N-cyanoethyl)-2-aminoethylthio>benzoic acid leads to o-benzoic acid hydrochloride.The cyclization of 1-<(N-carbomethoxyethyl)-2-aminoethylthio>benzoic acid in the presence of PCl3 gives 5-oxo-4-(carbomethoxyethyl)-6,7-benzoperhydro-1,4-thiazepine.

Full text of DOI:10.1007/BF00506034

Products guided by the article

Product name:o-benzoic acid

Cas No:79543-66-1

R&D Labs maybe for 79543-66-1

Nantong Chem-land Co., Ltd.

Contact:86 513 85512619

Address:Rm.1306, Building A, Wenfeng Mansion,168 Gongnong Road, Nantong Jiangsu China
TLS PHARMACEUTICAL CO.,LTD

Contact:0833-5590788/5590338/5590055

Address:Victory in the town of Red Star Village,Mount Emei City,industrial concentration area storage processing logistics parkpark
Nanjing Ruizhi Industry & Technologh Co.，Ltd.

Contact:+86-25-86808110

Address:441-4-A5,NO.12 Longzang Avenue,Yuhuatai District,210039,Nanjing
Hubei Sibo Technology Co.,Ltd.

Contact:0715-6597222

Address:Pan Jia Wan fan Lake Chemical Industrial Park ,Xianning City, Hubei, China
Changzhou naidechemical Co.Ltd

Contact:+86-519-82589807

Address:NO.25,Houyang street,Jintan,Changzhou City

Relevant to this article

Heavy-metal-containing polyhedral metallasiloxane derived from an aminosilanetriol: Synthesis and structural characterization of [(PbO) ₆(R₂Si₂O₃)₂] (R = (2,6.iPr₂C₆H₃)N(SiMe₃))

Doi:10.1021/om049417u
(2004)
SYNTHETIC APPLICATION OF LITHIATION REACTIONS - XVI: SYNTHESES OF (+/-)TETRAHYDROPALMATINE, (+/-)CANADINE, (+/-)STYLOPINE AND (+/-)SINACTINE

Doi:10.1016/S0040-4020(01)91915-5
(1983)
SYNTHESIS AND CYCLOADDITION REACTION OF 2,3-DIMETHYLENE-7-ISOPROPYLIDENEBENZONORBORNENE

Doi:10.1016/S0040-4039(01)90525-8
(1981)
Design and synthesis of new fluorinated ligands for the rhodium-catalyzed hydroformylation of alkenes in supercritical CO₂ and fluorous solvents

Doi:10.1016/S0022-1139(01)00473-0
(2001)
Molybdenum-catalyzed asymmetric allylation of 3-alkyloxindoles: Application to the formal total synthesis of (-)-physostigmine

Doi:10.1021/ja060560j
(2006)
Effect of Metal Ions in Organic Synthesis. Part 10. Synthesis and X-ray Crystal Structure of Some 1-(Arylamino)pyrrole Derivatives by Reaction of (Arylazo)alkenes and β-Dicarbonyl Compounds in the Presence of Copper(II) Chloride

Doi:10.1021/jo00343a016
(1982)

Article Doi