HETEROATOMIC DERIVATIVES OF AZIRIDINE. 12. REACTION OF 1-(CARBOMETHOXYALKYL)AZIRIDINES WITH THIOLS AND MERCAPTO ACIDS

DOI: 10.1007/BF00506034

Source and publish data:

Chemistry of Heterocyclic Compounds p. 679 - 681 (1981)

Update date:2022-09-26

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Authors:

Voronkov, M. G.

Knutov, V. I.

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Article abstract of DOI:10.1007/BF00506034

The reaction of 1-(carbomethoxyalkyl)aziridines with thiols and mercapto acids, which leads to the formation of the corresponding sulfides and esters of S-substituted N-(2-mercaptoethyl)amino acids, was studied.The acid hydrolysis of o-<(N-carbomethoxyethyl)-2-aminoethylthio>benzoic acid and o-<(N-cyanoethyl)-2-aminoethylthio>benzoic acid leads to o-benzoic acid hydrochloride.The cyclization of 1-<(N-carbomethoxyethyl)-2-aminoethylthio>benzoic acid in the presence of PCl3 gives 5-oxo-4-(carbomethoxyethyl)-6,7-benzoperhydro-1,4-thiazepine.

Full text of DOI:10.1007/BF00506034

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