Journal of Organic Chemistry p. 5050 - 5052 (1981)
Update date:2022-08-04
Topics:
Kaloustian, Moses K.
Nader, Randa B.
The sulfhydrolytic cleavage of O,N-dimethylbutyrolactamium and O,N-dimethylvalerolactamium tetrafluoroborates involves C-N scission under kinetic control (61 deg C, NaSH, Ac2O, CHCl3) but C-O cleavage under thermodynamic control (27 deg C, NaSH, acetone).
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