The Direct Conversion of α-Olefins into Vinyl- and Allyl-silanes catalysed by Rhodium Complexes

DOI: 10.1039/c39810000673

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 673 - 674 (1981)

Update date:2022-08-05

Topics:

Authors:

Millan, Andres

Towns, Elizabeth

Maitlis, Peter M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39810000673

At high α-olefin to Et3SiH ratios and at temperatures <= 40 deg C <(RhC5Me5)2Cl4> catalyses the formation of vinyl- and allyl-silanes; other rhodium complexes act similarly.

Full text of DOI:10.1039/c39810000673

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:1-(triethylsilyl)-1-heptene

Cas No:79643-96-2

R&D Labs maybe for 79643-96-2

Hefei TNJ chemical industry co.,ltd

website:https://www.tnjchem.com

Contact:+86-551-65418695

Address:B911 Xincheng Business Center, Qianshan Road, Hefei Anhui China
Daqing E-shine Chemical Co.,LTD

Contact:0086-024-31285112

Address:Hongweiyuan area, Ranghulu district
Shangyu Sanhechemicals Co.,LTD.

Contact:86-0571-56696839

Address:Num.2952,Nanhuan Road,Binjiang District,Hangzhou,China
Rudong Zhenfeng Yiyang Chemical Co., Ltd.

Contact:0513-84573047

Address:South Fengli Town, Rudong County, Jiangsu Province, China
Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

website:http://www.bjgreenchem.com/

Contact:+86-427-6515887

Address:301,302, 3rd Floor, Building C-7, Dongsheng Science Park, Northern Territory, Zhongguancun, No. 66, Xixiaokou Road, Haidian District, Beijing

Relevant to this article

Synthesis of Optically Active Spirohydantoins by Asymmetric Induction. Hydantoin Formation from Amino Nitriles and Chlorosulfonyl Isocyanate

Doi:10.1021/jo00142a016
(1982)
Synthesis of glycosyl phosphates from 1,2-orthoesters and application to in situ glycosylation reactions

Doi:10.1021/ol0603155
(2006)
Irreversible enzyme inhibitors. Inhibitors of guinea pig complement derived by quaternization of substituted pyridines with benzyl halides

Doi:10.1021/jm00231a001
(1976)
Doi:10.1071/CH9761223
(1976)
Palladium-Catalyzed Carbonylative Coupling of Aryl Iodides with Alkyl Bromides: Efficient Synthesis of Alkyl Aryl Ketones

Doi:10.1002/adsc.201800879
(2018)
Doi:10.1021/jo00422a023
(1977)

Article Doi