STERIC ASPECTS OF THE OXIDATION OF THIOKETONES BY SINGLET OXYGEN

DOI: 10.1246/cl.1982.89

Source and publish data:

Chemistry Letters p. 89 - 92 (1982)

Update date:2022-08-04

Topics:

Authors:

Ramnath, Narayan

Jayathertha, Vaidhya Rao

Ramesh, Varadaraj

Ramamurthy, Vaidhyanathan

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Article abstract of DOI:10.1246/cl.1982.89

Singlet oxygen oxidation of dialkyl thioketones yields the corresponding ketones and in some cases sulfoxides in varying amounts.Steric considerations on the reactive zwitterionic/diradical intermediates have been invoked to rationalise the product distribution.

Full text of DOI:10.1246/cl.1982.89

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