Journal of Organic Chemistry p. 5348 - 5351 (1981)
Update date:2022-08-03
Topics:
Manis, Paul A.
Rathke, Michael W.
(2,4,6-Tri-tert-butylphenoxy)dimethylsilyl chloride (TPS chloride, 3) is an inexpensive and readily prepared silylating agent for ketones.A variety of silyl enol ethers 4 were obtained by reaction of 3 with ketones.The acid- and base-catalyzed rates of hydrolysis of 4 were examined and compared to the rates for the corresponding trimethylsilyl and tert-butyldimethylsilyl enol ethers.
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(2017)Doi:10.1016/S0008-6215(00)81873-X
(1981)Doi:10.1039/P19930001819
(1993)Doi:10.1007/BF01188189
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(1950)Doi:10.1021/ja01477a021
(1961)
