THE BIRCH REDUCTION OF 2-ACYLTHIOPHENES. SYNTHESIS OF 1,3-DIENYL KETONES FROM 2-ACYLTHIOPHENES

DOI: 10.1246/cl.1981.1341

Source and publish data:

Chemistry Letters p. 1341 - 1344 (1981)

Update date:2022-08-04

Topics:

Authors:

Kosugi, Kimihiko

Anisimov, Alexander V.

Yamamoto, Hiroshi

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Article abstract of DOI:10.1246/cl.1981.1341

The Birch reduction of 2-acyl or 2-acyl-5-alkylthiophenes and subsequent alkylation by alkyl halides gave 2-acyl-2-alkyl or 2-acyl-2,5-dialkyl-2,5-dihydrothiophenes in good yields.Further, 1,3-dienyl ketones were obtained in good yields by the thermolysis

Full text of DOI:10.1246/cl.1981.1341

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