EXPLORATORY ORGANOMETAL-SULFUR CHEMISTRY; SYNTHESES AND UNUSUAL PROPERTIES OF RHENIUM CH2SR, CHSRR', AND =CHSR>+ COMPLEXES

DOI: 10.1016/S0022-328X(00)81018-9

Source and publish data:

Journal of Organometallic Chemistry p. C57 - C61 (1981)

Update date:2022-08-04

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Authors:

McCormick, Fred B.

Gladysz, J.A.

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Article abstract of DOI:10.1016/S0022-328X(00)81018-9

The methylidene complex <(η-C5H5)Re(NO)(PPh3)(CH2)>⁺PF6^- (I) yields kinetically labile sulfonium salts when treated with CH3SCH3, CH3SCH2C6H5, and (η-C5H5)Re(NO)(PPh3)(CH2SCH3) (V); the binuclear addict formed in the latter case, <(η

Full text of DOI:10.1016/S0022-328X(00)81018-9

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Product name:(C₅H₅)Re(NO)(P(C₆H₅)3)(CH₂S(CH₃)(CH₂C₆H₅))⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Re(NO)(P(C₆H₅)3)(CH₂S(CH₃)(CH₂C₆H₅))]PF₆

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