HAMMETT-CORRELATIONS, SOLVENT EFFECTS AND STEREOCHEMISTRY OF THE THERMAL DECARBOXYLATION OF 2-OXETANONES - EVIDENCE FOR A ZWITTERIONIC INTERMEDIATE

DOI: 10.1016/S0040-4039(00)71463-8

Source and publish data:

Tetrahedron Letters p. 751 - 754 (1980)

Update date:2022-08-03

Topics:

Authors:

Mulzer, Johann.

Zippel, Matthias

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)71463-8

Kinetic and stereochemical data of the thermal decarboxylation of 2-oxetanones (1 and 2) indicate that the reaction proceeds via a zwitterionic intermediate Z.

Full text of DOI:10.1016/S0040-4039(00)71463-8

Products guided by the article

Product name:(E)-2-benzylidene-3,3-dimethylbutanoic acid

Cas No:80228-22-4

R&D Labs maybe for 80228-22-4

Simagchem Corporation

website:http://www.simagchem.com

Contact:+86-592-2680277

Address:21/F Hualong Office Building,No.6 Hubin East Road, Xiamen,China
Langchem

Contact:+86+21-58956006 15800617331

Address:402 Room, 150# Cailun Road, Zhangjiang high tech park, Shanghai
Shandong united-rising pharmaceutical cooperation.,ltd.

Contact:008653187965009

Address:171No., Jing5 Road, Shizhong District, Jinan, China
Pengchen New Material Technology Co., Ltd.

Contact:+86-512-63680537

Address:99.6 km of national road 318, Meiyan Community,Pingwang Town, Wujiang District, Suzhou 215225
Rely Chemicals Ltd.

Contact:+86-518-81061113

Address:No. 8 Lingzhou Road, Lianyungang, Jiangsu, China

Relevant to this article

Lysine and Ornithine Analogues of Methotrexate as Inhibitors of Dihydrofolate Reductase

Doi:10.1021/jm00346a026
(1982)
Distinguishable Action between Acid-stable and Neutral α-Amylases from Shochu Koji (Aspergillus kawachii)

Doi:10.1271/bbb.61.1617
(1997)
Double elimination protocol for access to pyridine-containing arylene-ethynylenes

Doi:10.1246/cl.2004.1298
(2004)
SYNTHESIS AND HERBICIDAL ACTIVITY OF 4-CHLORO-2-NITROANILIDES OF &α,&β-UNSATURATED ACIDS

Doi:10.1007/BF01185267
(1981)
Solvolytic and Stable Ion Studies of 1,1'-Diadamantylmethyl Cations

Doi:10.1021/jo00345a029
(1982)
Diverse structures and remarkable oxidizing ability of triarylbismuthane oxides. Comparative study on the structure and reactivity of a series of triarylpnictogen oxides

Doi:10.1021/om0494115
(2004)

Article Doi