HAMMETT-CORRELATIONS, SOLVENT EFFECTS AND STEREOCHEMISTRY OF THE THERMAL DECARBOXYLATION OF 2-OXETANONES - EVIDENCE FOR A ZWITTERIONIC INTERMEDIATE

DOI: 10.1016/S0040-4039(00)71463-8

Source and publish data:

Tetrahedron Letters p. 751 - 754 (1980)

Update date:2022-08-03

Topics:

Authors:

Mulzer, Johann.

Zippel, Matthias

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)71463-8

Kinetic and stereochemical data of the thermal decarboxylation of 2-oxetanones (1 and 2) indicate that the reaction proceeds via a zwitterionic intermediate Z.

Full text of DOI:10.1016/S0040-4039(00)71463-8

Products guided by the article

Product name:(E)-2-benzylidene-3,3-dimethylbutanoic acid

Cas No:80228-22-4

R&D Labs maybe for 80228-22-4

zhangjiagang bonded areas banggao co;ltd

website:http://www.shunchangchem.com

Contact:0086-13921972933

Address:Dongsha Chemical Zone.Zhangjiagang, Jiangsu Province
Longhui qunfeng Chemical Co., Ltd

Contact:86-731-82173407

Address:South-east Industrial Park, Longhui County, Hunan Province, China
Feis International Trade Co,. Ltd

Contact:13961823444-18235944442

Address:Wuxi jiangsu
FOSHAN NANHAI ZHONGNAN PHARMACEUTICAL FACTORY

Contact:0086-0757-85609331

Address:XIAHENGTIAN INDUSTRIAL ZONE,SHAYONG VILLAGE,LISHUI TOWN
Shandong Yuanli Science and Technology Co., Ltd.

Contact:86-0536-6777557

Address:Zhuliu Industiral Park,Changle County

Relevant to this article

Lysine and Ornithine Analogues of Methotrexate as Inhibitors of Dihydrofolate Reductase

Doi:10.1021/jm00346a026
(1982)
Distinguishable Action between Acid-stable and Neutral α-Amylases from Shochu Koji (Aspergillus kawachii)

Doi:10.1271/bbb.61.1617
(1997)
Double elimination protocol for access to pyridine-containing arylene-ethynylenes

Doi:10.1246/cl.2004.1298
(2004)
SYNTHESIS AND HERBICIDAL ACTIVITY OF 4-CHLORO-2-NITROANILIDES OF &α,&β-UNSATURATED ACIDS

Doi:10.1007/BF01185267
(1981)
Solvolytic and Stable Ion Studies of 1,1'-Diadamantylmethyl Cations

Doi:10.1021/jo00345a029
(1982)
Diverse structures and remarkable oxidizing ability of triarylbismuthane oxides. Comparative study on the structure and reactivity of a series of triarylpnictogen oxides

Doi:10.1021/om0494115
(2004)

Article Doi