ACTIVATION OF POLYHALOALKANES BY PALLADIUM CATALYST. PREPARATION OF γ-TRICHLORO KETONES BY THE PALLADIUM CATALYZED ADDITION REACTION OF BROMOTRICHLOROMETHANE AND CARBON TETRACHLORIDE TO ALLYL ALCOHOLS

DOI: 10.1246/cl.1981.1605

Source and publish data:

Chemistry Letters p. 1605 - 1608 (1981)

Update date:2022-08-05

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Authors:

Nagashima, Hideo

Sato, Koji

Tsuji, Jiro

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Article abstract of DOI:10.1246/cl.1981.1605

The palladium catalyzed reaction of BrCCl3 and CCl4 with allyl alcohols with terminal double bonds afforded γ-trichloro ketones.Pd(OAc)2 combined with tri-o-tolylphosphine in the presence of a base gave the best results.

Full text of DOI:10.1246/cl.1981.1605

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