Journal of Organic Chemistry p. 1024 - 1027 (1982)
Update date:2022-08-02
Topics:
Nguyen, Tuyen T.
Amey, R. L.
Martin, J. C.
The synthesis of amino diol 2 in several steps from amino alcohol 5 allows the incorporation of the tridentate ligand in a pentacoordinate iodine species.This tridentate ligand provides stability to a hypervalent system due to its various structural features, including the five-membered rings.As a result, difluoroperiodinane 4 is isolated when iodo diol 10 is treated with 2 equiv of bromine trifluoride.This periodinane, which is a strong oxidizing reagent, demonstrated an exceptionally low reactivity.It does, however, rapidly oxidize trimethylchlorosilane or aqueoushydrogen chloride to give chlorine.Oxidation of p-chlorophenyl sulfide by 4 gives a mixture of sulfoxide and sulfone upon hydrolysis.
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Doi:10.1002/anie.201705909
(2017)Doi:10.1246/cl.1981.1511
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(1984)Doi:10.1016/S0022-328X(00)81029-3
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(1981)