CONDENSATION OF CF2Br2, CF2BrCl AND BrCF2CF2Br WITH ENAMINES AND YNAMINES

DOI: 10.1016/S0040-4039(01)81917-1

Source and publish data:

Tetrahedron Letters p. 3405 - 3408 (1981)

Update date:2022-08-03

Topics:

Authors:

Rico, I.

Cantacuzene, D.

Wakselman, C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)81917-1

BrCF2X (X: Cl, Br, BrCF2) react with enamines and ynamines.A radical chain mechanism is proposed.Halogen (Br or Cl) - fluorine exchange of α halodifluoromethylketones to α trifluoromethylketones using Bu4N(1+)*F(1-)*3H2O is examined.

Full text of DOI:10.1016/S0040-4039(01)81917-1

Products guided by the article

Product name:2-(Bromo-difluoro-methyl)-cyclohexanone

Cas No:80404-81-5

R&D Labs maybe for 80404-81-5

Huangshan Honghui Pharm Technology Co., Ltd.(expird)

website:http://www.honghuichem.com

Contact:18855958372

Address:Qingshan Wan No.1,Nanyuan Kou,SheXian Huangshan City,Anhui Province
Shandong Yuanli Science and Technology Co., Ltd.

Contact:86-0536-6777557

Address:Zhuliu Industiral Park,Changle County
X.T.Y Environ-Tech Co.,Ltd

Contact:+86-310-7092106

Address:Quzhou Modern & New Industrial Park, Handan, Hebei 057250, China
Hangzhou Zyter Biological & Chemical Technology Co., Ltd.

website:http://www.zyterpharm.com

Contact:+86-18858184290

Address:West Wenyi Road, Cangqian, Yuhang
Shanghai Pengkai Chemical Co.,Ltd

Contact:+86-21-60526671

Address:No.4226 Duzhuang Rd Minhang District Shanghai China

Relevant to this article

Preparation of Sugar-Derived β-Keto Phosphonates and Their Use in the Synthesis of Higher Sugars

Doi:10.1021/jo00100a047
(1994)
An Effective Strategy for the Preparation of α,β-Unsaturated Hydrazones and Pyrazole Derivatives. Synthetic Applications of β-Functionalized Phosphorus Compounds.

Doi:10.1016/S0040-4020(01)89404-7
(1994)
Additive effect of heparin on the photoinactivation of Escherichia coli using tricationic P-porphyrins

Doi:10.1016/j.bmcl.2017.10.032
(2017)
Phosphine-mediated regio- and stereoselective hydrocarboxylation of enynes

Doi:10.1021/ol4031556
(2014)
Redox-Neutral Aromatization of Cyclic Amines: Mechanistic Insights and Harnessing of Reactive Intermediates for Amine α- and β-C?H Functionalization

Doi:10.1002/chem.201603839
(2016)
Doi:10.1021/jm00329a034
(1965)

Article Doi