NICKELOCENE CHEMISTRY IV. NEW NICKELACYLES (η-C5H5)>PF6 (n = 1-3) FROM REACTIONS OF NICKELOCENE AND WITH BIS-YLIDS

DOI: 10.1016/S0022-328X(00)90111-6

Source and publish data:

Journal of Organometallic Chemistry p. 229 - 237 (1981)

Update date:2022-08-05

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Authors:

Booth, Brian L.

Smith, Kenneth G.

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Article abstract of DOI:10.1016/S0022-328X(00)90111-6

Nickelocene reacts with the bis-ylids, Ph3PCH(CH2)nCHPPh3 (n = 1-3) to give the new chelate complexes (η-C5H5)>PF6.The same compounds are also formed on reaction of the bis-ylids with .The compounds with ring siz

Full text of DOI:10.1016/S0022-328X(00)90111-6

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Product name:Ni(CHCH₃P(C₆H₅)3)2(C₅H₅)⁽¹⁺⁾*PF₆^(1-)=[Ni(CHCH₃P(C₆H₅)3)2(C₅H₅)]PF₆

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