STEREOCHEMICAL ARGUMENTS AGAINST A POSSIBLE CHLOROHYDRIN ROUTE IN THE CATALYTIC EPOXIDATION OF OLEFINS WITH NaOCl/Mn-porphyrins.

DOI: 10.1016/S0040-4039(00)88184-8

Source and publish data:

Tetrahedron Letters p. 3621 - 3624 (1983)

Update date:2022-09-26

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Authors:

Carvalho, Maria-Eliza De

Meunier, Bernard

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Article abstract of DOI:10.1016/S0040-4039(00)88184-8

The stereochemistry of the epoxidation of norbornene and 3-carene with the NaOCl/Mn(TPP)OAc system is the same as that observed with peracids, suggesting that the chlorohydrin route does not occur in this catalytic epoxidation.

Full text of DOI:10.1016/S0040-4039(00)88184-8

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