Inorganic Chemistry p. 2062 - 2064 (1982)
Update date:2022-08-03
Topics:
Gaffney, Thomas R.
Ibers, James A.
Addition of CS2 to RuClH(CO)(PCy3)2 affords the cation [RuH(CO)(S2CPCy3)(PCy3)2] +, which has been isolated as the tetraphenylborate salt. The closely related complex [RuCl(CO)(S2CPCy3)(PCy3)2][BPh 4] is formed when the zwitterion ligand S2CPCy3 is added to a methanol suspension of RuCl2(CO)(PCy3)2 and NaBPh4. The reaction of carbonyl sulfide with RuClH(CO)(PCy3)2 results in the formation of RuClH(CO)2(PCy3)2.
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Doi:10.1016/0040-4039(96)01752-2
(1996)Doi:10.1139/v65-093
(1965)Doi:10.1021/jo00348a032
(1982)Doi:10.1039/a900986h
(1999)Doi:10.1016/S0008-6215(00)85145-9
(1980)Doi:10.1021/ic00116a007
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