Journal of Organometallic Chemistry p. 193 - 198 (1981)
Update date:2022-08-04
Topics:
Nalesnik, Theodore E.
Freudenberger, John H.
Orchin, Milton
The tetrasubstituted ethylene, bifluorenylidene, reacts very rapidly (4.06*10-2 l mol-1 sec-1 at 0 deg C) with HCo(CO)4 to give bifluorenyl. α-Phenylacrylonitrile (atroponitrile) reacts even more rapidly under the same conditions (6.0 l mol-1 sec-1).Other highly substituted ethylenes react very slowly with HCo(CO)4, indicating considerable steric effects.The data are consistent with radical type intermediates.
View Moreshanghai hekang chemical co.ltd
Contact:021-54173790
Address:328 WuHe Road, Building #A, 2nd Floor, Minhang, Shanghai 201109, China
BrightGene Bio-Medical Technology Co., Ltd.
website:https://en.bright-gene.com/
Contact:+86-512-62551801
Address:Building C25 - C31, No. 218 Xinghu Road, Suzhou Industrial Park, Suzhou, Jiangsu, China.
website:https://www.finerchem.com
Contact:+86-531-88989536
Address:New Material Industrial Park, Jinan City, China
Shanghai Zhihua ChemTech Co., Ltd.
Contact:+86-13774313779
Address:Room 817 Suite B 3333 Shenjiang Road
Yixing Bluwat Chemicals Co., Ltd.
Contact:+86 510 87821568
Address:Yongan Road, Yixing Chemical Industrial Park, Yixing, Jiangsu, China
Doi:10.1134/S1070428016050018
(2016)Doi:10.1139/v81-498
(1981)Doi:10.1016/j.bmcl.2008.01.106
(2008)Doi:10.1021/jo048756u
(2004)Doi:10.1021/ja00370a077
(1982)Doi:10.1021/jm0497996
(2004)
