Journal of the Chemical Society. Perkin transactions I p. 2948 - 2951 (1981)
Update date:2022-08-06
Topics:
Callaghan, Patrick D.
Elliott, Arthur J.
Gandhi, Sham S.
Gibson, Martin S.
Mastalerz, Harold
Vukov, Darko J.
Reactions of N'-arylbenzothiohydrazides and of their N-acyl-derivatives with carboxylic anhydrides under various sets of conditions are shown to lead to 2-acylalkylidene-3-aryl-5-phenyl-2H-1,3,4-thiadiazolenes.The probable mechanism of formation of these compounds via the corresponding 2-alkylidenethiadiazolene as intermediate is discussed.
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