REACTIONS OF SUGAR THIO-ORTHOESTERS: NUCLEOPHILIC SUBSTITUTION OF AN ARYLTHIO GROUP DURING ZEMPLEN DEACYLATION

DOI: 10.1016/S0008-6215(00)80813-7

Source and publish data:

Carbohydrate Research p. 181 - 194 (1981)

Update date:2022-08-03

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Authors:

Backinowsky, Leon V.

Byramova, Narguiz E.

Tsvetkov, Yury E.

Betaneli, Vitali I.

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Article abstract of DOI:10.1016/S0008-6215(00)80813-7

Deacylation of acetylated and benzoylated sugar 1,2-thio-orthoesters bearing an S-aromatic residue with methanolic sodium methoxide is accompanied by inter- and intra-molecular nucleophilic substitution of the arylthio group with formation of the correspo

Full text of DOI:10.1016/S0008-6215(00)80813-7

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