Synlett p. 461 - 462 (1997)
Update date:2022-08-03
Topics:
Sugai, Masaharu
Tanino, Keiji
Kuwajima, Isao
A new synthetic method for medium-sized cyclic allenes and acetylenes was developed on the basis of a C-C bond cleavage directed by a silyl group. An enol triflate derived from 6-(silylmethyl)-10-siloxybicyclo[4.4.0]decan-2-one was heated at 150 °C in DMF to afford ten-membered allene in good yield. A cyclodecyne derivative was also prepared from the regioisomeric enol triflate.
View MoreShijiazhuang Yunxuan Im&Export Co.,Ltd.
Contact:+86-311-83037514
Address:No.6 Hongbin Road
Contact:+86-025-52406782
Address:8 Taizishan Rd., Yanjiang Industrial Development Area, Nanjing, Jiangsu, China.
ClickChem Technology Co., Limited
Contact:+86-0310-6519966/0531-52893837
Address:No.750 Shunhua Road, High-Tech Zone, Jinan city, Shandong China
Weifang Dongxing Chitosan Factory
website:http://dxchitosan.lookchem.com/
Contact:13475651157
Address:Weifang city ,shandong province
Angelisun(Chongqing) Pharmaceutical Co., LTD.
Contact:+86-23-68030926-816
Address:D1-7 Tech & Entrepreneurs Park, Kecheng Road, Erlang Hi-Tech Areas, Chongqing, China
Doi:10.1021/ic00136a056
(1982)Doi:10.1021/jo00348a018
(1982)Doi:10.1016/0039-128X(81)90084-2
(1981)Doi:10.1007/BF00513300
(1982)Doi:10.1016/j.bmc.2014.12.005
(2015)Doi:10.1021/jo00134a029
(1982)
