Journal of the Chemical Society, Dalton Transactions p. 2529 - 2536 (1981)
Update date:2022-08-05
Topics:
Funabiki, Takuzo
Yoshida, Satohiro
Cyanocobaltate prepared at CN:Co <5:1 in water in the presence of alkali and under an atmosphere of hydrogen reacts readily with mono-olefins having electron-withdrawing substituents to give a dark red solution.Hydrogen-1 and 13C n.m.r. spectra of the solutions in D2O clearly indicate that ?-olefin complexes of cyanocobaltate are formed.The solutions also exhibit characteristic bands near 450 nm.The stoicheiometry of complex formation has been studied using PhCH=C(CN)2 and monitored by the absorbance of the complex at 440 nm.These results indicate that a new type of ?-olefin-cobalt(I) complex,
Shanghai Demand Chemical Co., ltd，China
Contact:86-021-55237578/55239122
Address:Room 3H, No.578, Yingkou Road, Yangpu District, Shanghai, China
ShangHai BMG Chemical Co., Ltd
Contact:+86-13524845543
Address:Room 602, no 291 sikai road shanghai
Wuhan Kemi-Works Chemical Co., Ltd
website:http://www.kemiworks.com
Contact:86-27-85736489
Address:Rm. 1503, No. 164, Jianghan North Rd., Wuhan, 430022 China
chengdu firsterchem Pharmaceutical Co., Ltd.
Contact:028-66825849
Address:chengdu
Hangzhou Kai Peng Biotechnology Co., Ltd.
Contact:86-571-89939007
Address:NO. 499, Wensan West Road, Xihu District, Hangzhou, 310012, China
Doi:10.1016/S0008-6215(00)81904-7
(1982)Doi:10.1016/j.farmac.2005.02.002
(2005)Doi:10.1002/chem.201902150
(2019)Doi:10.1248/cpb.29.3320
(1981)Doi:10.1016/0040-4020(94)01137-O
(1995)Doi:10.1021/ja01177a082
(1949)
