Stereocontrolled Synthesis of Gorgosterol

DOI: 10.1039/c39830001180

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1180 - 1182 (1983)

Update date:2022-08-04

Topics:

Authors:

Terasawa, Takeshi

Hirano, Yutaka

Fujimoto, Yoshinori

Ikekawa, Nobuo

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Article abstract of DOI:10.1039/c39830001180

Gorgosterol (1), a C30 marine sterol containing cyclopropane in the side chain, has been stereoselectively synthesized utilizing orthoester Claisen rearrangement and intramolecular alkylative cyclopropanation.

Full text of DOI:10.1039/c39830001180

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