PHOTOCHEMISTRY OF BICYCLIC δ-THIA-α,β-UNSATURATED KETONES A VINYLKETENE MECHANISM

DOI: 10.1016/S0040-4039(01)82973-7

Source and publish data:

Tetrahedron Letters p. 4421 - 4424 (1981)

Update date:2022-07-29

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Authors:

Miyashi, Tsutomu

Suto, Nobukazu

Yamaki, Takayuki

Mukai, Toshio

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Article abstract of DOI:10.1016/S0040-4039(01)82973-7

Photolyses and pyrolyses of bicyclic δ-thia-α,β-unsaturated ketones (8) and (1a) were investigated.Experimental and spectroscopic evidences support a vinylketene mechanism both for photolysis and pyrolysis.

Full text of DOI:10.1016/S0040-4039(01)82973-7

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