Tetrahedron Letters p. 4421 - 4424 (1981)
Update date:2022-07-29
Topics:
Miyashi, Tsutomu
Suto, Nobukazu
Yamaki, Takayuki
Mukai, Toshio
Photolyses and pyrolyses of bicyclic δ-thia-α,β-unsaturated ketones (8) and (1a) were investigated.Experimental and spectroscopic evidences support a vinylketene mechanism both for photolysis and pyrolysis.
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