THE REACTION OF ALLYL IODIDE WITH KETONES IN THE PRESENCE OF CERIUM AMALGAM. AN EFFICIENT METHOD FOR THE PREPARATION OF HOMOALLYLIC ALCOHOLS

DOI: 10.1016/S0040-4039(01)92399-8

Source and publish data:

Tetrahedron Letters p. 4987 - 4988 (1981)

Update date:2022-08-04

Topics:

Authors:

Imamoto, Tsuneo

Hatanaka, Yasuo

Tawarayama, Yoshinori

Yokoyama, Masataka

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)92399-8

Allyl iodide reacts in situ with cerium amalgam to generate allyl cerium iodide, which in turn reacts with ketones to yield homoallylic alcohols in good yields.

Full text of DOI:10.1016/S0040-4039(01)92399-8

Products guided by the article

Product name:2-Naphthalen-2-yl-1-phenyl-propan-2-ol

Cas No:81336-13-2

R&D Labs maybe for 81336-13-2

Taizhou Sunny Chemical Co.,Ltd

Contact:+86-523-86920899 +86-13951172783

Address:No.11 Xingyuang road, Gaoyong Chemical Industry Park, Gaogang Jiangsu China
Zhejiang Haizhou Pharmaceutical Co., Ltd.

website:https://www.haizhoupharma.com/

Contact:+86-576-88221016

Address:No. 19, Donghai 5th Avenue, Yanhai Industrial Zone, Linhai, Zhejiang, China
Shanghai Sunway Pharmaceutical Technology Co.,Ltd.

Contact:+86-21-5161 3915

Address:Shanghai YangPu
Zhangjiagang Jianing Import & Export Co.,Ltd.

Contact:086-512-55379012 13913607595

Address:NO.1 Guotai North Road Zhangjiagang Economic Development Zone,215600,Jiangsu,China
Guangxi Nanning Guangtai Agriculture Chemical Co.,Ltd

Contact:+86-771-2311266

Address:Room703,Building12, Software Park Phase II,NO.68,Keyuan Road,Nanning City,Guangxi,China

Relevant to this article

Synthesis of highly functionalized chiral nitriles by radical fragmentation of β-hydroxy azides. Convenient transformation of aldononitriles into 1,4- and 1,5-iminoalditols

Doi:10.1021/jo049026p
(2004)
A study of transesterification of chiral (-)-pinanediol methylboronic ester with various structurally modified diols

Doi:10.1007/s00706-007-0681-7
(2007)
Enzymatic production of l-menthol by a high substrate concentration tolerable esterase from newly isolated Bacillus subtilis ECU0554

Doi:10.1002/adsc.200800412
(2009)
On the Absolute Configuration of (+)-Indane-1-carboxylic Acid

Doi:10.1002/hlca.19820650135
(1982)
N-H insertion reactions of Boc-amino acid amides: Solution- and solid-phase synthesis of pyrazinones and pyrazines

Doi:10.1021/ol047933a
(2004)
Naphtho[1',2':5,6]pyrano[2,3-b][1,5]benzodiazepine derivatives

Doi:10.1002/jhet.5570180827
(1981)

Article Doi