Reductive Cyclization of Mercurial Enones

DOI: 10.1021/jo00132a064

Source and publish data:

Journal of Organic Chemistry p. 2231 - 2232 (1982)

Update date:2022-08-03

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Authors:

Danishefsky, Samuel

Chackalamannil, Samuel

Uang, Biing-Jiun

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Article abstract of DOI:10.1021/jo00132a064

A series of enones containing pendant isolated olefinic linkages was prepared.Solvomercuration could be conducted specifically at the isolated double bond.Treatment of these systems with sodium trimethoxyborohydride results in reductive cyclization.

Full text of DOI:10.1021/jo00132a064

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