A convenient method for bromosulfenylation: Reactions of sulfenamides with olefins in the presence of POBr3

Article abstract of DOI:10.1080/10426509908044968

A general method for the one-pot transformation of alkenes into abromoalkyl-arylsulfides has been proposed based on the sulfenylation reaction by means of sulfenamides in the presence of phosphorus oxibromide. The plausible reaction mechanism and the results of reactions with a number of model alkenes such as cyclohexene, 1-heptene, norbornene and other from the bicyclo[2.2.1]heptane series are discussed.

Full text of DOI:10.1080/10426509908044968

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Phosphorus, Sulfur, and Silicon
and the Related Elements
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A CONVENIENT METHOD FOR
BROMOSULFENYLATION:
REACTIONS OF SULFENAMIDES
WITH OLEFINS IN THE
PRESENCE OF POBr3
Nikolai V. Zyk a , Elena K. Beloglazkina a , Rimma
Gazzaeva b , Vladimir S. Tyurin a & Igor D. Titanyuk a
a Department of Chemistry , Moscow State
University , Moscow, Russia , 119899
b Hetagurov North-Osetia State University , Kutuzova
str, 60-3-113, Vladikavkaz, Russia , 362000
Published online: 04 Oct 2006.
To cite this article: Nikolai V. Zyk , Elena K. Beloglazkina , Rimma Gazzaeva ,
Vladimir S. Tyurin & Igor D. Titanyuk (1999) A CONVENIENT METHOD FOR
BROMOSULFENYLATION: REACTIONS OF SULFENAMIDES WITH OLEFINS IN THE PRESENCE
OF POBr3 , Phosphorus, Sulfur, and Silicon and the Related Elements, 155:1, 33-45,
DOI: 10.1080/10426509908044968
To link to this article: http://dx.doi.org/10.1080/10426509908044968
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