Tetrahedron Asymmetry p. 715 - 738 (1997)
Update date:2022-08-04
Topics:
Langer, Falk
Puentener, Kurt
Stuermer, Rainer
Knochel, Paul
The reaction of functionalized diorganozincs with chlorodiorganophosphines provides polyfunctional phosphines in good yields. Especially attractive is the hydroboration/boron-zinc exchange sequence which allows the conversion of functionalized olefins into polyfunctional phosphines in a one-pot procedure. Several new chiral phosphines have been prepared starting from readily available chiral olefins (terpenes) and their efficiency in asymmetric hydrogenation reactions has been evaluated.
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