STUDY OF THE STEREOCHEMISTRY OF SILVER(I) BIS(PYRIDINE-2-CARBALDEHYDE-IMINE) TRIFLATE COMPLEXES IN SOLUTION: APPLICATION OF INEPT 109Ag AND 1H-NMR

DOI: 10.1016/S0022-328X(00)87437-9

Source and publish data:

Journal of Organometallic Chemistry p. C27 - C30 (1982)

Update date:2022-08-04

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Authors:

Stein, Gerard C. van

Koten, Gerard van

Brevard, Christian

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Article abstract of DOI:10.1016/S0022-328X(00)87437-9

IL2>(O3SCF3) complexes have been obtained from the 2/1 reaction of pyridine-2-carbaldehyde-imine (L) with AgO3SCF3.INEPT 109Ag and 1H-<109Ag> NMR studies of 2>(O3SCF3) reveal that the tetrahedral Ag^IL2 cation of this complex exists below 235 K in two diastereoisomeric forms with a strong preference for one of the molecular configurations (probably the Λ(S)(S)).

Full text of DOI:10.1016/S0022-328X(00)87437-9

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Product name:Ag(CH₃C₅NH₃CHNC₆H₁₁)2⁽¹⁺⁾*O₃SCF₃^(1-)=Ag(CH₃C₅H₃NCHNC₆H₁₁)2O₃SCF₃

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