
Journal of Organometallic Chemistry p. 281 - 290 (1985)
Update date:2022-09-26
Topics:
Oesterle, Rainer
Maringgele, Walter
Meller, Anton
Cyclo-1-oxa-3,5-diaza-2,4,6-triboranes (A) and cyclo-1,3-dioxa-5-aza-2,4,6-triboranes (B) have been prepared by four different methods: (1) from mixtures of hexamethyldisilazanes and hexamethyldisiloxane with CH3BBr2 (A and B); (2) from (CH3)3SiN2 and CH3BBr2 (B); (3) from cyclo-1-oxa-3,5-diaza-2,4,6-trisilanes and CH3BBr2 (A); and (4) from CH3BA).The products and some by-products were characterized by mass and NMR (1H, 11B, 29Si) spectra.Substances which were separated from the by-products were also analysed.
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