A NEW METHOD FOR THE SYNTHESIS OF β-HYDROXYESTERS BY USING METALLIC TIN

DOI: 10.1246/cl.1982.161

Source and publish data:

Chemistry Letters p. 161 - 164 (1982)

Update date:2022-08-04

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Authors:

Harada, Taira

Mukaiyama, Teruaki

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Article abstract of DOI:10.1246/cl.1982.161

Metallic tin or activated metallic tin, prepared by reduction of stannous chloride with lithium aluminum hydride, smoothly reacts with α-haloesters to yield tin enolates, which in turn react with carbonyl compounds under mild conditions to give, after hydrolysis, β-hydroxyesters in high yields.

Full text of DOI:10.1246/cl.1982.161

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