Chemistry Letters p. 161 - 164 (1982)
Update date:2022-08-04
Topics:
Harada, Taira
Mukaiyama, Teruaki
Metallic tin or activated metallic tin, prepared by reduction of stannous chloride with lithium aluminum hydride, smoothly reacts with α-haloesters to yield tin enolates, which in turn react with carbonyl compounds under mild conditions to give, after hydrolysis, β-hydroxyesters in high yields.
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