Tetrahedron Letters p. 6329 - 6332 (1993)
Update date:2022-08-04
Topics:
Jones
Turner
Howard
The synthesis of an enantiomeric pair of enaminoesters from phenylglycine is described. Conjugate addition to α,β-enones, reductive cyclization-fragmentation to octahydroimidazopyridines and further reduction to remove the auxiliary atoms, completes a new route to homochiral piperidines in which the enaminoesters function as homochiral 'ethanal enamines'.
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