Mechanisms in a Biomimetic Hydroxylation of a Chemical Probe: 5-Nitroacenaphthene

DOI: 10.1021/jo00313a001

Source and publish data:

Journal of Organic Chemistry p. 6233 - 6234 (1990)

Update date:2022-08-04

Topics:

Authors:

Khanna, Rajive K.

Sutherlin, Jody S.

Lindsey, David

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Article abstract of DOI:10.1021/jo00313a001

5-Nitroacenaphthene is hydroxylated by oxometalloporphyrin complexes of chromium, iron, and manganese via hydrogen atom abstraction pathways with charge separation in the transition state dependent on the electrophilicity of the oxygen atom in these model oxygenases.

Full text of DOI:10.1021/jo00313a001

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