Journal of Organometallic Chemistry p. C14 - C16 (1982)
Update date:2022-08-05
Topics:
Canty, Allan J.
Minchin, Nigel J.
Tris(1-pyrazolyl)methane (HCpz3) reacts with Pt(CH3)2(COD) to form Pt(CH3)2(HCpz3), and when this complex is heated in pyridine metallation of the pyrazole ring at C(5) occurs to form Pt(CH3)(HCpz2(pzH-1))(py).A triphenylphosphine derivative, Pt(CH3)(HCpz2(pzH-1))(PPh3)2, when slowly heated to 185 deg C forms Pt(HCpz2(pzH-1))(C6H4PPh2); this complex has both the nitrogen and phosphorus donor ligands metallated to form six and four-membered rings, respectively.
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(1982)Doi:10.1016/S0040-4039(01)81823-2
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(2002)Doi:10.1134/S1070428018120242
(2018)Doi:10.1002/jps.2600521222
(1963)
