
Tetrahedron Letters p. 3047 - 3048 (1981)
Update date:2022-08-05
Topics:
Hanack, Michael
Kuehnle, Adolf
Tropyliumbromide (1) reacts with AgSCF3 to form 7-Trifluoromethylthiocycloheptatriene (6), which on oxidation with p-nitroperbenzoic acid does not form 7-Trifluoromethylsulfonylcycloheptatriene (3a) but the trifluormethylsulfinate 4a.
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(2007)