Tetrahedron p. 3713 - 3721 (1981)
Update date:2022-08-05
Topics:
Varlet, J. M.
Collignon, N.
Savignac, Ph.
Diethyl 2-oxo-alkylphosphonates undergo reductive amination in the presence of an amine and sodium cyanohydridoborate (NaBH3CN) in MeOH at Ph 7-7.5.Studies with a large variety of ketophosphonates show that the reaction rate is very sensitive to steric hi
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