
Journal of the Chemical Society. Perkin transactions II p. 1637 - 1640 (1983)
Update date:2022-08-03
Topics:
Briggs, Andrew J.
Evans, Christopher M.
Glenn, Robert
Kirby, Anthony J.
Acetal <6; R=2,4-(NO2)2C6H3> is rigidly fixed in the equatorial conformation.As a result the lone-pair electrons on the ring oxygen cannot assist C-OR cleavage, and the compound is hydrolysed ca. 1013 times more slowly than a comparable axial t
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